no, those are not formatted for MV - and that will give you several problems.
The RPG-Makers work with fixed size tilesheets that are a lot smaller than the sheets you got from that package (at least based on the last picture example). It is easy to cut down tilesheets to the required size, but it will require some planning from you as you will be unable to use all tiles in a single tilesheet and will need to use different tilesets for different maps.
Unfortunately the second problem is the reason why the RMs can get away with smaller tilesets: the autotiles for the A1 to A4 tilesheets.
The autotiles are special mixes of tile sequences that the engine uses to dynamically create dozens of different tiles on the map. None of the tiles you got will be autotiles, and ONLY the A5 slot can handle non-autotiled ground tiles.
That restricts the number of ground tiles you can easily convert and use.
You'll have to convert at least some of the other ground tiles to autotiles to be able to continue to use them, and that is more difficult. Search the official blog for a topic "anatomy of an autotile", that tutorial should help you get started.